Author Affiliations
Abstract
1 Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
2 Institute of Zhejiang University - Quzhou, Quzhou, 324000, People’s Republic of China
3 Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, People’s Republic of China
4 School of Biological and Chemical Engineering, NingboTech University, Ningbo 315100, People’s Republic of China
5 Department of Physics, Tamkang University, New Taipei, 25137 Taiwan, People’s Republic of China
6 Australian Carbon Materials Centre (A-CMC), School of Chemical Engineering, University of New South Wales, Sydney, NSW 2051, Australia
Metal–organic frameworks (MOFs) have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity, but the limited catalytic activity and stability has hampered their practical use in water splitting. Herein, we develop a bond length adjustment strategy for optimizing naphthalene-based MOFs that synthesized by acid etching Co-naphthalenedicarboxylic acid-based MOFs (donated as AE-CoNDA) to serve as efficient catalyst for water splitting. AE-CoNDA exhibits a low overpotential of 260 mV to reach 10 mA cm-2 and a small Tafel slope of 62 mV dec-1 with excellent stability over 100 h. After integrated AE-CoNDA onto BiVO4, photocurrent density of 4.3 mA cm-2 is achieved at 1.23 V. Experimental investigations demonstrate that the stretched Co–O bond length was found to optimize the orbitals hybridization of Co 3d and O 2p, which accounts for the fast kinetics and high activity. Theoretical calculations reveal that the stretched Co–O bond length strengthens the adsorption of oxygen-contained intermediates at the Co active sites for highly efficient water splitting.
Nano-Micro Letters
2024, 16(1): 175
Author Affiliations
Abstract
1 China University of Mining and Technology, School of Materials and Physics, Xuzhou, China
2 Southeast University, State Key Laboratory of Millimeter Waves, Nanjing, China
3 Soochow University, School of Physical Science and Technology and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou, China
4 Soochow University, Institute for Advanced Study, Suzhou, China
The pseudo-magnetic field, an artificial synthetic gauge field, has attracted intense research interest in the classical wave system. The strong pseudo-magnetic field is realized in a two-dimensional photonic crystal (PhC) by introducing the uniaxial linear gradient deformation. The emergence of the pseudo-magnetic field leads to the quantization of Landau levels. The quantum-Hall-like edge states between adjacent Landau levels are observed in our designed experimental implementation. The combination of two reversed gradient PhCs gives rise to the spatially nonuniform pseudo-magnetic field. The propagation of the large-area edge state and the interesting phenomenon of the snake state induced by the nonuniform pseudo-magnetic field is experimentally demonstrated in a PhC heterostructure. This provides a good platform to manipulate the transport of electromagnetic waves and to design useful devices for information processing.
photonic crystal pseudo-magnetic field edge state snake state 
Advanced Photonics Nexus
2024, 3(2): 026011
吕新杰 1,2,4,*杨彬 5姚红权 1,3汪小涵 3[ ... ]祝世宁 1,2,3,4,**
作者单位
摘要
1 南京大学固体微结构物理国家重点实验室,江苏 南京 210093
2 南京大学现代工程与应用科学学院,江苏 南京 210023
3 南京大学物理学院,江苏 南京 210093
4 南京大学人工微结构科学与技术协同创新中心,江苏 南京 210093
5 南京信息工程大学大气物理学院,江苏 南京 210044
为了实现远程气体探测,基于由超晶格材料构成的光参量振荡器,研制了一台双波长输出的中红外激光器。该光参量振荡器通过种子注入的方式,实现了纳秒级窄线宽的中红外脉冲激光输出,重复频率为500 Hz,单脉冲能量超过1 mJ,并能够对准2.6~4.0 μm波长范围内的NO、NO2和SO2的吸收峰。通过气体动态排放实验,在远程气体探测实验中对该激光器进行了验证。
光参量 窄线宽 光谱 中红外激光器 
激光与光电子学进展
2024, 61(1): 0114001
Author Affiliations
Abstract
1 Tianjin University, Ministry of Education, School of Precision Instruments and Opto-Electronics Engineering, Key Laboratory of Opto-Electronics Information Technology Tianjin, China
2 University College London, Department of Electronic and Electrical Engineering, London, United Kingdom
3 University of Mining and Technology, School of Materials Science and Physics, Xuzhou, China
4 Tianjin University, School of Electrical and Information Engineering, Tianjin, China
5 Southeast University, School of Information Science and Engineering, State Key Laboratory of Millimeter Waves, Nanjing, China
6 Zhejiang University, College of Information Science and Electronic Engineering, Key Laboratory of Micro-Nano Electronic Devices and Smart Systems of Zhejiang Province, Hangzhou, China
Unlike conventional topological edge states confined at a domain wall between two topologically distinct media, the recently proposed large-area topological waveguide states in three-layer heterostructures, which consist of a domain featuring Dirac points sandwiched between two domains of different topologies, have introduced the mode width degree of freedom for more flexible manipulation of electromagnetic waves. Until now, the experimental realizations of photonic large-area topological waveguide states have been exclusively based on quantum Hall and quantum valley-Hall systems. We propose a new way to create large-area topological waveguide states based on the photonic quantum spin-Hall system and observe their unique feature of pseudo-spin-momentum-locking unidirectional propagation for the first time in experiments. Moreover, due to the new effect provided by the mode width degree of freedom, the propagation of these large-area quantum spin-Hall waveguide states exhibits unusually strong robustness against defects, e.g., large voids with size reaching several unit cells, which has not been reported previously. Finally, practical applications, such as topological channel intersection and topological energy concentrator, are further demonstrated based on these novel states. Our work not only completes the last member of such states in the photonic quantum Hall, quantum valley-Hall, and quantum spin-Hall family, but also provides further opportunities for high-capacity energy transport with tunable mode width and exceptional robustness in integrated photonic devices and on-chip communications.
large-area quantum spin-Hall waveguide states strong robustness against defects high-capacity energy transport mode width degree of freedom 
Advanced Photonics Nexus
2024, 3(1): 016009
袁汉钦 1铁清木 2赵唯贤 3,4邱旭蒙 3,4[ ... ]杨斌 3,4
作者单位
摘要
1 海军装备部驻合肥地区军事代表室,合肥230000
2 云南大学 软件学院,昆明650504
3 中国电子科技集团有限公司第五十五研究所,南京210016
4 国家平板显示工程技术研究中心,南京210016
针对当前液晶显示器前壳缝隙开口处的填充材料工艺设计复杂的问题,选取高导电性的金属粒子填充层作为导电面层,碳布层作为屏蔽面层,柔性硅橡胶作为中间基体层,设计一种层状结构导电橡胶。通过结构设计实现了导电橡胶低硬度和高导电性的协同。结果表明,当硅橡胶的硬度为35,体积电阻率为0.01 Ω·cm时可满足显示器产品的密封、防水和电磁屏蔽应用要求。
液晶显示器 硅橡胶 高导电性 层状结构 TFT-LCD silicone rubber high conductivity multi-layered structure 
光电子技术
2023, 43(3): 255
杨科 1,*薛媛元 1贾波 2白宣庆 1[ ... ]陈娟 1
作者单位
摘要
1 西安应用光学研究所,陕西 西安 710065
2 陆装西安军代局驻西安地区第八军代室,陕西 西安 710065
损伤阈值测量装置是强激光技术的重要技术指标,主要用于强激光光学元件的研制和测试,而同步触发模块作为模块之间时序的控制器,是研制损伤阈值测量装置的关键技术之一。介绍了一种用于激光损伤阈值测量装置的同步触发模块及方法。设计了基于现场可编程门阵列(field programmable gate array,FPGA)为主控芯片的硬件方案,通过上位机操控软件设置同步触发参数,来控制各路输出同步信号的宽度和各路信号之间的时序,可极大提高同步触发的精度和效率。通过实验验证,同步脉冲信号之间的调节精度为2 ns,同步脉冲信号的最小宽度为10 ns,满足激光损伤阈值测量装置的要求。
损伤阈值 同步触发 FPGA damage threshold synchronous trigger field programmable gate array 
应用光学
2023, 44(6): 1228
李作恩 1,2鞠学平 1胡春晖 1,*颜昌翔 1,3[ ... ]杨斌 5
作者单位
摘要
1 中国科学院 长春光学精密机械与物理研究所,吉林 长春 130033
2 中国科学院大学,北京 100049
3 中国科学院大学 材料与光电研究中心,北京 100049
4 航天系统部 装备部 装备项目管理中心,北京 100094
5 长光禹辰信息技术与装备(青岛)有限公司,山东 青岛 266000
为了满足高精度偏振探测要求,通道型偏振光谱仪在设计时需要考虑望远镜组偏振效应的影响,并对其进行相应的分析和优化。首先,分析望远镜组偏振效应的影响因素,采用坐标变换和穆勒矩阵连乘法建立了考虑膜系偏振效应的望远镜组穆勒矩阵模型,并带入通道型偏振光谱仪偏振解调模型。接着,通过同时控制S光和P光的透过率和相位延迟,设计相应的低偏振效应膜系。最后,运用偏振光线追迹的方法对镀有不同膜系的望远镜组进行偏振效应仿真。仿真结果表明,在580 nm和750 nm波长处,低偏振效应膜系与高偏振效应膜系的偏振探测精度变化不明显。而在420 nm波长处,低偏振效应膜系相较于常用膜系的边缘视场偏振探测精度提高了3.22%。低偏振效应膜系可以有效降低通道型偏振光谱仪望远镜组偏振效应,提高仪器的偏振探测精度。
偏振光谱相机 偏振效应 斯托克斯矢量 穆勒矩阵 polarization spectrum camera polarization effect stokes vector muller matrix 
液晶与显示
2023, 38(12): 1728
作者单位
摘要
1 湖南大学 材料科学与工程学院,湖南 长沙 410082
2 中国电子科技集团公司第二十六研究所,重庆400060
该文提出了一种获得相对带宽约为70.61%的基于氮化铝薄膜的超宽带薄膜体声波谐振器(FBAR)滤波器的设计方法,即在中心频率为6.5 GHz下滤波器的带宽为4.835 GHz。仿真分析表明,通过串并联电感的方式,并在电感端串并联电容,可消除因增加电感而带来的谐波谐振点干扰对带通的影响,实现了FBAR滤波器的超宽带。该工作开辟了设计和制作带宽超过3 GHz的超宽带体声波滤波器的新途径。
薄膜体声波谐振器 FBAR滤波器 超宽带体声波滤波器 氮化铝 thin film bulk acoustic resonator FBAR filter ultra-wideband bulk acoustic wave filter aluminum nitride 
压电与声光
2023, 45(5): 663
谭智强 1,2卜令兵 1,2,*杨彬 1,2
作者单位
摘要
1 南京信息工程大学大气物理学院中国气象局气溶胶与云降水重点开放实验室,江苏 南京 210044
2 南京信息工程大学气象灾害预警与评估协同创新中心,江苏 南京 210044
研制了一套使用种子源直接放大激光器和时分复用收发的新型瑞利多普勒激光雷达。激光器通过对种子源进行多级光纤和固体功率放大,获得了稳定的60 W高平均功率脉冲激光输出。脉冲激光通过时分复用发射系统向垂直、正西和正北方向交替发射进入大气,从三个方向接收到的激光大气回波信号经过光纤合束后送入同一套碘分子吸收池中进行多普勒鉴频。基于上述系统设计开展了系统探测性能仿真研究和实验验证对比分析,仿真结果表明,系统能够在时间分辨率为30 min、垂直高度分辨率为1 km条件下完成大气温度和经纬向水平风速的同步测量,其中60 km高度处温度理论测量误差为1.99 K,经纬向水平风速理论测量误差为4.78 m/s。系统的验证实验结果表明,60 km高度处大气温度的实测误差为2.4 K,经纬向水平风速的实测误差分别为8.7 m/s和 8.5 m/s,反演结果与大气模式和卫星探测结果进行对比呈现了较好的一致性。
传感器 激光雷达 中高层大气 瑞利散射 碘分子吸收池 多普勒效应 
光学学报
2023, 43(24): 2428001
作者单位
摘要
1 上海理工大学能源与动力工程学院/上海市动力工程多相流动与传热重点实验室, 上海 200093
2 上海航天动力技术研究所, 上海 201109
火焰燃烧参数能直接反映火焰燃烧状态, 并对燃烧过程进行诊断、 预测和优化。 火焰温度及辐射率是燃烧状态的重要表征参数, 火焰温度及辐射率的准确测量对于建立燃烧模型、 优化燃烧过程和控制污染物排放有着非常重要的意义。 随着数字图像技术与光谱学的发展, 多光谱成像技术逐步应用于火焰燃烧温度及辐射率测量。 针对光谱仪空间分辨率低和RGB彩色相机光谱分辨率低的问题, 多光谱成像技术能获得兼顾空间分辨率及光谱分辨率的火焰光谱图像, 实现火焰温度及辐射率分布测量, 具有高时空分辨率、 响应快速及测温范围宽等优点。 因此, 提出了基于多光谱成像技术的火焰温度及辐射率测量方法, 搭建标准高温黑体辐射实验测量系统, 对多光谱相机665~960 nm波段开展高温黑体辐射响应系数标定实验, 获得多光谱相机25波段光谱响应标定系数, 通过四阶多项式拟合建立多光谱相机各波段下仪器响应值与理论辐射强度之间的关系, 并开展多光谱成像技术测量验证实验, 结果显示温度与辐射率测量的相对偏差分别小于1%与4%。 在此基础上, 以蜡烛火焰为研究对象, 建立了火焰多光谱成像测量系统, 获得了蜡烛火焰多光谱辐射图像, 基于普朗克辐射定律参数拟合方法, 实现了蜡烛火焰温度与辐射率分布测量。 测量结果表明: 火焰竖直平面上火焰中心区温度及辐射率均高于火焰上部和底部; 蜡烛火焰温度测量结果范围约为1 350~2 050 K, 火焰中心区最高温度约为2 050 K; 蜡烛火焰辐射率测量结果范围约为0.04~0.36, 火焰中心区最高辐射率为0.36。 测量结果与蜡烛火焰燃烧过程及辐射特性分布规律一致。
多光谱成像 燃烧诊断 辐射测温法 蜡烛火焰 火焰辐射率分布 Multispectral imaging Combustion diagnostics Radiation temperature measurement Candle flame Flame emissivity distribution 
光谱学与光谱分析
2023, 43(11): 3644

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